Gallium(III)corrole-BODIPY hybrid: novel photophysical properties and first observation of B-F∙∙∙F interactions.
نویسندگان
چکیده
Anchoring a BODIPY onto Ga(III)corrole via a meso-β linkage facilitated PeT in polar solvents, which quenched the fluorescence, and is further confirmed by electrochemical studies. The triad exhibits unprecedented crystal emission, which is not known for a corrole derivative, due to unique packing. Compound 4 hosts the first example of a novel B-F∙∙∙F interaction as well.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 44 48 شماره
صفحات -
تاریخ انتشار 2015